Which instrument should I use? This provides about 3x the amount of signal per scan compared to the autox probe, since it is optimized for 1H detect.
Signal-to-noise scales as the square root of the number of scans, so the 3x signal boost corresponds to about a 9x time savings. In other words, if you run a 9 hour HSQC overnight on the using the autox probe, you could obtain the same signal to noise ratio using the penta probe for 1 hour. You will see your 1H spectrum as your direct F2 axis and your 13C spectrum as your indirect F1 axis.
You will see a cross peak for any 1H connected to a 13C that is one bond away. Several betterments was proposed to increase sensivity, reduce artifacts like 1 J CH coupling , measure coupling constants, and others.
Category : NMR experiment. Jump to: navigation , search. Angewandte Chemie International Edition , 46 39 , Hilton , Patrick A. Irish , Kirill A. Blinov , Antony J. Magnetic Resonance in Chemistry , 45 10 , Journal of Heterocyclic Chemistry , 44 5 , Martin , Patrick A.
Irish , Bruce D. Magnetic Resonance in Chemistry , 45 8 , Tetrahedron Letters , 48 23 , Optimizing sensitivity and resolution in time-shared NMR experiments. Magnetic Resonance in Chemistry , 45 4 , Pair your accounts. Your Mendeley pairing has expired.
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